free radical:
NOUN: An atom or group of atoms that has at least one unpaired electron and is therefore unstable and highly reactive. In animal tissues, free radicals can damage cells and are believed to accelerate the progression of cancer, cardiovascular disease, and age-related diseases.
L-arginine is therefore not a free radical, but an amino acid, that promotes nitric oxide that is a free radical with a chemical signature of NO. NO2 would be the stable compound. Nirtic oxide is not a very reactive free radical and therefore not as damaging, but it plays a vital role in the male erection.